diff --git a/Library/Homebrew/extend/ENV/super.rb b/Library/Homebrew/extend/ENV/super.rb
index b4f0dfcac0..660b9b3a3c 100644
--- a/Library/Homebrew/extend/ENV/super.rb
+++ b/Library/Homebrew/extend/ENV/super.rb
@@ -173,11 +173,22 @@ module Superenv
   end
 
   def determine_library_paths
-    PATH.new(
+    paths = [
       keg_only_deps.map(&:opt_lib),
       HOMEBREW_PREFIX/"lib",
-      homebrew_extra_library_paths,
-    ).existing
+    ]
+
+    if compiler == :llvm_clang
+      if MacOS::CLT.installed?
+        paths << "/usr/lib"
+      else
+        paths << "#{MacOS.sdk_path}/usr/lib"
+      end
+      paths << Formula["llvm"].opt_lib.to_s
+    end
+
+    paths += homebrew_extra_library_paths
+    PATH.new(paths).existing
   end
 
   def determine_dependencies